Molybdenum (VI) Imido Complexes Derived from Chelating Phenols: Synthesis, Characterization and ɛ-Caprolactone ROP Capability

Molybdenum (VI) Imido Complexes Derived from Chelating Phenols: Synthesis, Characterization and ɛ-Caprolactone ROP Capability

Reaction of the bulky bi-phenols 2,2′-RCH[4,6-(t-Bu)2C6H2OH]2 (R = Me L1MeH2, Ph L1PhH2) with the bis(imido) molybdenum(VI) tert-butoxides [Mo(NR1)(NR2)(Ot-Bu)2] (R1 = R2 = 2,6-C6H3-i-Pr2; R1 = t-Bu, R2 = C6F5) afforded, following the successive removal of tert-butanol, the complexes [Mo(NC6H3i-Pr2-...

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Bibliographic Details
Main Authors: Yahya Al-Khafaji, Timothy J. Prior, Mark R. J. Elsegood, Carl Redshaw
Format: Article
Language:English
Published: MDPI AG 2015-11-01
Series:Catalysts
Subjects:
molybdenum (VI)
imido
phenolate
chelate
crystal structures
ε-caprolactone
ring opening polymerization
Online Access:http://www.mdpi.com/2073-4344/5/4/1928

Internet

http://www.mdpi.com/2073-4344/5/4/1928

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