Cationic polymerization of β-pinene in the presence of alkylaluminum chlorides as catalysts

Cationic polymerization of β-pinene in the presence of alkylaluminum chlorides as catalysts

Cationic polymerization of β-pinene, a naturally occurring monomer, was studied in the presence of different alkylaluminum chlorides ((iBu)3Al2Cl3, Et3Al2Cl3 и Мe2AlCl) in the solvent mixture dichloromethane/methylcyclohexane (DCM/MCH) at –78 °C. The effect of catalyst concentration [(iBu)3Al2Cl3] a...

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Bibliographic Details
Main Authors: Maksim I. Hulnik, Olga V. Kuharenko, Sergei V. Kostjuk
Format: Article
Language:Belarusian
Published: Belarusian State University 2020-08-01
Series:Журнал Белорусского государственного университета: Химия
Subjects:
β-pinene
cationic polymerization
alkylaluminum chlorides
controlled cationic polymerization
electron donor
proton trap
Online Access:https://journals.bsu.by/index.php/chemistry/article/view/3269

Internet

https://journals.bsu.by/index.php/chemistry/article/view/3269

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