Crystal structure of a low-spin poly[di-μ3-cyanido-di-μ2-cyanido-bis(μ2-2-ethylpyrazine)dicopper(I)iron(II)]

Crystal structure of a low-spin poly[di-μ3-cyanido-di-μ2-cyanido-bis(μ2-2-ethylpyrazine)dicopper(I)iron(II)]

In the title metal–organic framework, [Fe(C6H8N2)2{Cu(CN)2}2]n, the low-spin FeII ion lies at an inversion centre and displays an elongated octahedral [FeN6] coordination environment. The axial positions are occupied by two symmetry-related bridging 2-ethylpyrazine ligands, while the equatorial posi...

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Bibliographic Details
Main Authors: Sofiia V. Partsevska, Dina D. Naumova, Igor P. Matushko, Olesia I. Kucheriv, Il'ya A. Gural'skiy
Format: Article
Language:English
Published: International Union of Crystallography 2019-08-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
ethylpyrazine
dicyanocuprate
iron(II)
copper(I)
bimetallic
metal–organic framework
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989019009496

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http://scripts.iucr.org/cgi-bin/paper?S2056989019009496

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