A surface-stabilized ozonide triggers bromide oxidation at the aqueous solution-vapour interface

A surface-stabilized ozonide triggers bromide oxidation at the aqueous solution-vapour interface

Heterogeneous oxidation of bromide in atmospheric aqueous environments has long been suspected to be accelerated at the interface between aqueous solution and air. Here, the authors provide spectroscopic, kinetic and theoretical evidence for a rate limiting, surface active ozonide formed at the inte...

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Bibliographic Details
Main Authors: Luca Artiglia, Jacinta Edebeli, Fabrizio Orlando, Shuzhen Chen, Ming-Tao Lee, Pablo Corral Arroyo, Anina Gilgen, Thorsten Bartels-Rausch, Armin Kleibert, Mario Vazdar, Marcelo Andres Carignano, Joseph S. Francisco, Paul B. Shepson, Ivan Gladich, Markus Ammann
Format: Article
Language:English
Published: Nature Publishing Group 2017-09-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-017-00823-x

Internet

https://doi.org/10.1038/s41467-017-00823-x

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