An unsymmetrical dinuclear scandium complex comprising salophen ligands [H2salophen = N,N′-bis(salicylidene)-1,2-phenylenediamine]

An unsymmetrical dinuclear scandium complex comprising salophen ligands [H2salophen = N,N′-bis(salicylidene)-1,2-phenylenediamine]

Treatment of scandium nitrate tetrahydrate with the tetradentate ligand H2salophen [N,N′-bis(salicylidene)-1,2-phenylenediamine] afforded the yellow dinuclear complex Sc(NO3)2(μ-salophen)Sc(salophen)(EtOH) or [Sc2(C20H14N2O2)2(NO3)2(C2H6O)] (systematic name: (ethanol-κO)bis(nitrato-κ2O,O′){μ-2,2′-[1...

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Bibliographic Details
Main Authors: Volker Lorenz, Phil Liebing, Liane Hilfert, Sabine Busse, Frank T. Edelmann
Format: Article
Language:English
Published: International Union of Crystallography 2019-02-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
scandium
salophen ligand
Schiff base
dinuclear scandium complex
crystal structure
π–π stacking
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989019000094

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http://scripts.iucr.org/cgi-bin/paper?S2056989019000094

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