Cobalt(II) Complexes with N,N,N-Scorpionates and Bidentate Ligands: Comparison of Hydrotris(3,5-dimethylpyrazol-1-yl)borate Tp* vs. Phenyltris(4,4-dimethyloxazolin-2-yl)borate ToM to Control the Structural Properties and Reactivities of Cobalt Centers

Cobalt(II) Complexes with N,N,N-Scorpionates and Bidentate Ligands: Comparison of Hydrotris(3,5-dimethylpyrazol-1-yl)borate Tp* vs. Phenyltris(4,4-dimethyloxazolin-2-yl)borate ToM to Control the Structural Properties and Reactivities of Cobalt Centers

Scorpionate ligands Tp* (hydrotris(3,5-dimethylpyrazol-1-yl)borate) and ToM (tris(4,4-dimethyloxazolin-2-yl)phenylborate) complexes of cobalt(II) with bidentate ligands were synthesized. Both Tp* and ToM coordinate to cobalt(II) in a tridentate fashion when the bidentate ligand is the less hindered...

Full description

Bibliographic Details
Main Authors: Toshiki Nishiura, Takahiro Uramoto, Yuichiro Takiyama, Jun Nakazawa, Shiro Hikichi
Format: Article
Language:English
Published: MDPI AG 2018-06-01
Series:Molecules
Subjects:
scorpionate ligand
borate
cobalt
oxidation
Online Access:http://www.mdpi.com/1420-3049/23/6/1466

Internet

http://www.mdpi.com/1420-3049/23/6/1466

Similar Items