Novel Carbon-Carbon Bond Oxidative Cleavage of Hexabenzylhexaazaisowurtzitane by n-BuONO and (NH4)2Ce(NO3)6

Novel Carbon-Carbon Bond Oxidative Cleavage of Hexabenzylhexaazaisowurtzitane by n-BuONO and (NH4)2Ce(NO3)6

Treatment of 2,4,6,8,10,12-hexabenzyl-2,4,6,8,10,12-hexaazatetracyclo-[5.5.0.05,9.03,11]dodecane (1) with n-butyl nitrite or ammonium cerium nitrate results in novel C(1)-C(7) oxidative cleavage to give 1,3,4,5,7,8-hexabenzyl-cis-cisoid-cis-hexahydro-1H,5H-diimidazolinium[4,5-b:4',5'-e]pyr...

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Bibliographic Details
Main Authors: Yong-Zhong Yu, Jian-Guang Sun, Hong Yan, Xiao-Pei Guan
Format: Article
Language:English
Published: MDPI AG 1999-03-01
Series:Molecules
Subjects:
Oxidative cleavage
hexabenzylhexaazaisowurtzitane
iminium cation
Online Access:http://www.mdpi.com/1420-3049/4/3/69/

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http://www.mdpi.com/1420-3049/4/3/69/

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