Biomimetic approach to the catalytic enantioselective synthesis of tetracyclic isochroman

Biomimetic approach to the catalytic enantioselective synthesis of tetracyclic isochroman

General and stereoselective synthesis of tetracyclic isochroman-containing polyketide oligomers is challenging. Here, the authors report on an Au(I)/chiral Sc(III) bimetallic catalyst for a biomimetic asymmetric hetero-Diels–Alder reaction for in-situ generation of isochromene and ortho-quinonemethi...

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Bibliographic Details
Main Authors: Xiangfeng Lin, Xianghui Liu, Kai Wang, Qian Li, Yan Liu, Can Li
Format: Article
Language:English
Published: Nature Publishing Group 2021-08-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-021-25198-y

Internet

https://doi.org/10.1038/s41467-021-25198-y

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