Incorporation of μ3-CO3 into an MnIII/MnIV Mn12 cluster: {[(cyclam)MnIV(μ-O)2MnIII(H2O)(μ-OH)]6(μ3-CO3)2}Cl8·24H2O

Incorporation of μ3-CO3 into an MnIII/MnIV Mn12 cluster: {[(cyclam)MnIV(μ-O)2MnIII(H2O)(μ-OH)]6(μ3-CO3)2}Cl8·24H2O

The centrosymmetric title cluster, hexaaquadi-μ3-carbonato-hexacyclamhexa-μ2-hydroxido-dodeca-μ2-oxido-hexamanganese(IV)hexamanganese(III) octachloride tetracosahydrate, [Mn12(CO3)2O12(OH)6(C10H24N4)6(H2O)6]Cl8·24H2O, has two μ3-CO3 gr...

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Bibliographic Details
Main Authors: Marilyn M. Olmstead, Ben B. Levaton
Format: Article
Language:English
Published: International Union of Crystallography 2010-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810034999

Internet

http://scripts.iucr.org/cgi-bin/paper?S1600536810034999

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