An enantiomerically pure siderophore type ligand for the diastereoselective 1 : 1 complexation of lanthanide(III) ions

An enantiomerically pure siderophore type ligand for the diastereoselective 1 : 1 complexation of lanthanide(III) ions

A facile synthesis of a highly preorganized tripodal enterobactine-type ligand 1a-H3 consisting of a chiral C3-symmetric macrocyclic peptide and three tridentate 2-amido-8-hydroxyquinoline coordinating units is presented. Complex formation with various metal ions (Al3+, Ga3+, Fe3+, La3+ and Eu3+) wa...

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Bibliographic Details
Main Authors: Markus Albrecht, Olga Osetska, Thomas Abel, Gebhard Haberhauer, Eva Ziegler
Format: Article
Language:English
Published: Beilstein-Institut 2009-12-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
CD spectroscopy
enterobactin
lanthanide
macrocycles
molecular modeling
Online Access:https://doi.org/10.3762/bjoc.5.78

Internet

https://doi.org/10.3762/bjoc.5.78

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