Ring-opening reaction of 2,5-dioctyldithieno[2,3-b:3',2'-d]thiophene in the presence of aryllithium reagents

Ring-opening reaction of 2,5-dioctyldithieno[2,3-b:3',2'-d]thiophene in the presence of aryllithium reagents

In this paper, the ring-opening reaction of 2,5-dioctyldithieno[2,3-b:3',2'-d]thiophene with aryllithium in THF at low temperature to generate 2'-arylthio-3,3'-bithiophene-2-carbaldehydes is studied. Nine examples are explored and all the products are characterized by 1H NMR, 13C...

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Bibliographic Details
Main Authors: Hao Zhong, Jianwu Shi, Jianxun Kang, Shaomin Wang, Xinming Liu, Hua Wang
Format: Article
Language:English
Published: Beilstein-Institut 2013-04-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
aryllithium reagents
2'-arylthio-3,3'-bithiophene-2-carbaldehyde
dithieno[2,3-b:3',2'-d]thiophene
nucleophilicity
ring-opening reaction
Online Access:https://doi.org/10.3762/bjoc.9.87

Internet

https://doi.org/10.3762/bjoc.9.87

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