Methyl-torsion-facilitated internal energy delocalization following electronic excitation in m-fluorotoluene: Can meta and para substitution be directly compared?
Coupling between vibrations, and between vibrations and torsions—a generalization of intramolecular vibrational redistribution (IVR)—provides routes to internal energy delocalization, which can stabilize molecules following photoexcitation. Following earlier work on p-fluorotoluene (pFT), this study...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
AIP Publishing LLC
2020-12-01
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| Series: | AIP Advances |
| Online Access: | http://dx.doi.org/10.1063/5.0032146 |