A Cu(II)–ATP complex efficiently catalyses enantioselective Diels–Alder reactions

A Cu(II)–ATP complex efficiently catalyses enantioselective Diels–Alder reactions

ATP acts as a co-substrate in enzyme catalysed reactions, but can also specifically bind metal ions. Here, the authors show that ATP interacts with copper ions and forms a Cu(II)-ATP complex that efficiently catalyses Diels-Alder reactions, and determine ATP residues that are essential for this acti...

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Bibliographic Details
Main Authors: Changhao Wang, Qianqian Qi, Wenying Li, Jingshuang Dang, Min Hao, Shuting Lv, Xingchen Dong, Youkun Gu, Peizhe Wu, Wenyue Zhang, Yashao Chen, Jörg S. Hartig
Format: Article
Language:English
Published: Nature Publishing Group 2020-09-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-020-18554-x

Internet

https://doi.org/10.1038/s41467-020-18554-x

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