Kinetic Studies that Evaluate the Solvolytic Mechanisms of Allyl and Vinyl Chloroformate Esters

Kinetic Studies that Evaluate the Solvolytic Mechanisms of Allyl and Vinyl Chloroformate Esters

At 25.0 °C the specific rates of solvolysis for allyl and vinyl chloroformates have been determined in a wide mix of pure and aqueous organic mixtures. In all the solvents studied, vinyl chloroformate was found to react significantly faster than allyl chloroformate. Multiple correlation analyses of...

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Bibliographic Details
Main Authors: Malcolm J. D'Souza, Aaron F. Givens, Peter A. Lorchak, Abigail E. Greenwood, Stacey L. Gottschall, Shannon E. Carter, Dennis N. Kevill
Format: Article
Language:English
Published: MDPI AG 2013-04-01
Series:International Journal of Molecular Sciences
Subjects:
allyl chloroformate
vinyl chloroformate
mechanisms
solvolysis
nucleophilicity
ionizing power
π electron cloud
Grunwald-Winstein equation
Linear Free Energy Relationships (LFERs)
Online Access:http://www.mdpi.com/1422-0067/14/4/7286

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http://www.mdpi.com/1422-0067/14/4/7286

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