Part 1. Reduction of S-alkyl-thionocarbonates and related compounds in the presence of trialkylboranes/air

A new, mild, and environment friendly process for the reduction of S-alkyl-thionocarbonates, iodides and related compounds to the corresponding hydrocarbons at room temperature with good to excellent yields is described. This method uses a trialkylborane in excess (Et3B or Bu3B) and air.

Bibliographic Details
Main Authors: Jean Boivin, Van Tai Nguyen
Format: Article
Language:English
Published: Beilstein-Institut 2007-12-01
Series:Beilstein Journal of Organic Chemistry
Online Access:https://doi.org/10.1186/1860-5397-3-45