Part 1. Reduction of S-alkyl-thionocarbonates and related compounds in the presence of trialkylboranes/air

Part 1. Reduction of S-alkyl-thionocarbonates and related compounds in the presence of trialkylboranes/air

A new, mild, and environment friendly process for the reduction of S-alkyl-thionocarbonates, iodides and related compounds to the corresponding hydrocarbons at room temperature with good to excellent yields is described. This method uses a trialkylborane in excess (Et3B or Bu3B) and air.

Bibliographic Details
Main Authors: Jean Boivin, Van Tai Nguyen
Format: Article
Language:English
Published: Beilstein-Institut 2007-12-01
Series:Beilstein Journal of Organic Chemistry
Online Access:https://doi.org/10.1186/1860-5397-3-45
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spelling doaj-e13502f052024505ac42e8658f3e17422021-03-02T09:40:29ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972007-12-01314510.1186/1860-5397-3-451860-5397-3-45Part 1. Reduction of S-alkyl-thionocarbonates and related compounds in the presence of trialkylboranes/airJean Boivin0Van Tai Nguyen1Institut de Chimie des Substances Naturelles, C.N.R.S., Avenue de la Terrasse, 91198 Gif-sur-Yvette, FranceInstitut de Chimie des Substances Naturelles, C.N.R.S., Avenue de la Terrasse, 91198 Gif-sur-Yvette, FranceA new, mild, and environment friendly process for the reduction of S-alkyl-thionocarbonates, iodides and related compounds to the corresponding hydrocarbons at room temperature with good to excellent yields is described. This method uses a trialkylborane in excess (Et3B or Bu3B) and air.https://doi.org/10.1186/1860-5397-3-45
collection DOAJ
language English
format Article
sources DOAJ
author Jean Boivin
Van Tai Nguyen
spellingShingle Jean Boivin
Van Tai Nguyen
Part 1. Reduction of S-alkyl-thionocarbonates and related compounds in the presence of trialkylboranes/air
Beilstein Journal of Organic Chemistry
author_facet Jean Boivin
Van Tai Nguyen
author_sort Jean Boivin
title Part 1. Reduction of S-alkyl-thionocarbonates and related compounds in the presence of trialkylboranes/air
title_short Part 1. Reduction of S-alkyl-thionocarbonates and related compounds in the presence of trialkylboranes/air
title_full Part 1. Reduction of S-alkyl-thionocarbonates and related compounds in the presence of trialkylboranes/air
title_fullStr Part 1. Reduction of S-alkyl-thionocarbonates and related compounds in the presence of trialkylboranes/air
title_full_unstemmed Part 1. Reduction of S-alkyl-thionocarbonates and related compounds in the presence of trialkylboranes/air
title_sort part 1. reduction of s-alkyl-thionocarbonates and related compounds in the presence of trialkylboranes/air
publisher Beilstein-Institut
series Beilstein Journal of Organic Chemistry
issn 1860-5397
publishDate 2007-12-01
description A new, mild, and environment friendly process for the reduction of S-alkyl-thionocarbonates, iodides and related compounds to the corresponding hydrocarbons at room temperature with good to excellent yields is described. This method uses a trialkylborane in excess (Et3B or Bu3B) and air.
url https://doi.org/10.1186/1860-5397-3-45
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AT vantainguyen part1reductionofsalkylthionocarbonatesandrelatedcompoundsinthepresenceoftrialkylboranesair
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