Enantioselective construction of six- and seven-membered triorgano-substituted silicon-stereogenic heterocycles

Enantioenriched medium-sized silicon-stereogenic heterocycles are in high demand due to the potential use in functional materials. Here, the authors show a rhodium-catalyzed enantioselective synthesis of six- and seven-membered tri-organosubstituted silicon-stereogenic heterocycles.

Bibliographic Details
Main Authors:	Shuyou Chen, Delong Mu, Pei-Lin Mai, Jie Ke, Yingzi Li, Chuan He
Format:	Article
Language:	English
Published:	Nature Publishing Group 2021-02-01
Series:	Nature Communications
Online Access:	https://doi.org/10.1038/s41467-021-21489-6

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spelling	doaj-e18bfca0d9cd44e487b14b10aa4f75bb2021-02-23T10:35:30ZengNature Publishing GroupNature Communications2041-17232021-02-011211910.1038/s41467-021-21489-6Enantioselective construction of six- and seven-membered triorgano-substituted silicon-stereogenic heterocyclesShuyou Chen0Delong Mu1Pei-Lin Mai2Jie Ke3Yingzi Li4Chuan He5Shenzhen Grubbs Institute and Department of Chemistry, Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and TechnologyShenzhen Grubbs Institute and Department of Chemistry, Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and TechnologyShenzhen Grubbs Institute and Department of Chemistry, Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and TechnologyShenzhen Grubbs Institute and Department of Chemistry, Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and TechnologyShenzhen Grubbs Institute and Department of Chemistry, Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and TechnologyShenzhen Grubbs Institute and Department of Chemistry, Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and TechnologyEnantioenriched medium-sized silicon-stereogenic heterocycles are in high demand due to the potential use in functional materials. Here, the authors show a rhodium-catalyzed enantioselective synthesis of six- and seven-membered tri-organosubstituted silicon-stereogenic heterocycles.https://doi.org/10.1038/s41467-021-21489-6
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Shuyou Chen Delong Mu Pei-Lin Mai Jie Ke Yingzi Li Chuan He
spellingShingle	Shuyou Chen Delong Mu Pei-Lin Mai Jie Ke Yingzi Li Chuan He Enantioselective construction of six- and seven-membered triorgano-substituted silicon-stereogenic heterocycles Nature Communications
author_facet	Shuyou Chen Delong Mu Pei-Lin Mai Jie Ke Yingzi Li Chuan He
author_sort	Shuyou Chen
title	Enantioselective construction of six- and seven-membered triorgano-substituted silicon-stereogenic heterocycles
title_short	Enantioselective construction of six- and seven-membered triorgano-substituted silicon-stereogenic heterocycles
title_full	Enantioselective construction of six- and seven-membered triorgano-substituted silicon-stereogenic heterocycles
title_fullStr	Enantioselective construction of six- and seven-membered triorgano-substituted silicon-stereogenic heterocycles
title_full_unstemmed	Enantioselective construction of six- and seven-membered triorgano-substituted silicon-stereogenic heterocycles
title_sort	enantioselective construction of six- and seven-membered triorgano-substituted silicon-stereogenic heterocycles
publisher	Nature Publishing Group
series	Nature Communications
issn	2041-1723
publishDate	2021-02-01
description	Enantioenriched medium-sized silicon-stereogenic heterocycles are in high demand due to the potential use in functional materials. Here, the authors show a rhodium-catalyzed enantioselective synthesis of six- and seven-membered tri-organosubstituted silicon-stereogenic heterocycles.
url	https://doi.org/10.1038/s41467-021-21489-6
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Enantioselective construction of six- and seven-membered triorgano-substituted silicon-stereogenic heterocycles

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