Two Carbonylations of Methyl Iodide and Trimethylamine to Acetic acid and N,N-Dimethylacetamide by Rhodium(I) Complex: Stability of Rhodium(I) Complex under Anhydrous Condition
Rhodium(I)-complex [Rh(CO)2I2−] (1) catalyzed two carbonylations of methyl iodide and trimethylamine in NMP (1-methyl-2-pyrolidone) to acetic acid and DMAC (N,N-dimethylacetamide) in the presence of calcium oxide and water. The carbonylation of trimethylamine continued during the carbonylation and...
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| Format: | Article |
| Language: | English |
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MDPI AG
2015-11-01
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| Series: | Catalysts |
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| Online Access: | http://www.mdpi.com/2073-4344/5/4/1969 |