2,12-Diaza[6]helicene: An Efficient Non-Conventional Stereogenic Scaffold for Enantioselective Electrochemical Interphases

2,12-Diaza[6]helicene: An Efficient Non-Conventional Stereogenic Scaffold for Enantioselective Electrochemical Interphases

The new configurationally stable, unsymmetrical 2,12-diaza[6]helicene was synthesized as a racemate and the enantiomers were separated in an enantiopure state by semi-preparative HPLC on chiral stationary phase. Under selected alkylation conditions it was possible to obtain both the enantiopure 2-&l...

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Bibliographic Details
Main Authors: Francesca Fontana, Benedetta Bertolotti, Sara Grecchi, Patrizia Romana Mussini, Laura Micheli, Roberto Cirilli, Matteo Tommasini, Simona Rizzo
Format: Article
Language:English
Published: MDPI AG 2021-08-01
Series:Chemosensors
Subjects:
azahelicenes
chiral voltammetry
enantiodiscrimination
ionic liquids
chiral additives
Online Access:https://www.mdpi.com/2227-9040/9/8/216

Internet

https://www.mdpi.com/2227-9040/9/8/216

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