Synthesis of (±)-africanol
Two diastereomers of africanol, compounds 1a and 1b, were obtained exclusively through a methodology which employed, as the key step, the nBuLi mediated intramolecular cyclization of the vinyl iodide 5. A similar cyclization of 19 provided exclusively the tertiary allylic alcohol 20. Africanol could...
Main Authors: | , , |
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Format: | Article |
Language: | English |
Published: |
Sociedade Brasileira de Química
2000-01-01
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Series: | Journal of the Brazilian Chemical Society |
Subjects: | |
Online Access: | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532000000500012 |