Synthesis, Characterisation and Reactions of Phosphine-Substituted Alkynylboronates and Alkynyltrifluoroborate Salts

Synthesis, Characterisation and Reactions of Phosphine-Substituted Alkynylboronates and Alkynyltrifluoroborate Salts

The synthesis and structural characterisation of phosphine-substituted alkynylboronates is reported. A P(III)-centred alkynylboronate (2) was prepared that showed little evidence for the conjugation of the P-lone pair to the boron via the alkyne π-system, as judged by X-ray crystallography studies...

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Bibliographic Details
Main Authors: Jérôme F. Vivat, Sylvestre P. J. T. Bachollet, Harry Adams, Joseph P. A. Harrity
Format: Article
Language:English
Published: MDPI AG 2014-12-01
Series:Molecules
Subjects:
alkynylboronate
trifluoroborate salt
conjugation
phosphine
cross-coupling
Online Access:http://www.mdpi.com/1420-3049/19/12/21324

Internet

http://www.mdpi.com/1420-3049/19/12/21324

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