Solventless Synthesis of Poly(pyrazolyl)phenyl-methane Ligands and Thermal Transformation of Tris(3,5-dimethylpyrazol-1-yl)phenylmethane

Solventless Synthesis of Poly(pyrazolyl)phenyl-methane Ligands and Thermal Transformation of Tris(3,5-dimethylpyrazol-1-yl)phenylmethane

The solventless synthesis of tris(pyrazolyl)phenylmethane ligands of formula C6H5C(PzR2)3 (R = H, Me), starting from PhCCl3 and 3,5-dimethylpyrazole (PzMe2) or pyrazole (Pz) was performed. The sterically crowded C6H5C(PzMe2)3 is thermally transformed into the bis(pyrazolyl)(p-pyrazolyl)phenylmethane...

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Bibliographic Details
Main Authors: Edith Rodríguez-Venegas, Efrén V. García-Báez, Francisco J. Martínez-Martínez, Alejandro Cruz, Itzia I. Padilla-Martínez
Format: Article
Language:English
Published: MDPI AG 2017-03-01
Series:Molecules
Subjects:
thermal synthesis
tris(pyrazolyl)phenylmethane
bis(pyrazolyl)phenylmethane
poly(pyrazolyl)methane
three-bladed propeller
X-ray molecular structure
Online Access:http://www.mdpi.com/1420-3049/22/3/441

Internet

http://www.mdpi.com/1420-3049/22/3/441

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