Anomalous hysteresis and current fluctuations in cyclic voltammograms at microelectrodes due to Ag leaching from Ag/AgCl reference electrodes
We observe anomalous cyclic voltammograms (CVs) measured with microelectrodes immersed in a Fe(CN)63−/4− redox buffer, which exhibit pronounced hysteresis, current fluctuations, a current level that increases with successive scans, and current suppression at positive potentials in the anodic scan. C...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
Elsevier
2019-08-01
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| Series: | Electrochemistry Communications |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S1388248119301626 |