Enantioselective Diels–Alder reaction of anthracene by chiral tritylium catalysis

The combination of the trityl cation and a chiral weakly coordinating Fe(III)-based bisphosphate anion was used to develop a new type of a highly active carbocation Lewis acid catalyst. The stereocontrol potential of the chiral tritylium ion pair was demonstrated by its application in an enantiosele...

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Bibliographic Details
Main Authors: Qichao Zhang, Jian Lv, Sanzhong Luo
Format: Article
Language:English
Published: Beilstein-Institut 2019-06-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Online Access:https://doi.org/10.3762/bjoc.15.129