Transmetalation from Magnesium–NHCs—Convenient Synthesis of Chelating π-Acidic NHC Complexes

Transmetalation from Magnesium–NHCs—Convenient Synthesis of Chelating π-Acidic NHC Complexes

The synthesis of chelating <i>N</i>-heterocyclic carbene (NHC) complexes with considerable &#960;-acceptor properties can be a challenging task. This is due to the dimerization of free carbene ligands, the moisture sensitivity of reaction intermediates or reagents, and challenges ass...

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Bibliographic Details
Main Authors: Julian Messelberger, Annette Grünwald, Philipp Stegner, Laura Senft, Frank W. Heinemann, Dominik Munz
Format: Article
Language:English
Published: MDPI AG 2019-05-01
Series:Inorganics
Subjects:
NHC
transmetalation
magnesium
palladium
carbene
Online Access:https://www.mdpi.com/2304-6740/7/5/65

Internet

https://www.mdpi.com/2304-6740/7/5/65

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