Asymmetric Transfer Hydrogenation of Arylketones Catalyzed by Enantiopure Ruthenium(II)/Pybox Complexes Containing Achiral Phosphonite and Phosphinite Ligands

Asymmetric Transfer Hydrogenation of Arylketones Catalyzed by Enantiopure Ruthenium(II)/Pybox Complexes Containing Achiral Phosphonite and Phosphinite Ligands

A family of complexes of the formula <i>trans</i>-[RuCl<sub>2</sub>(L)(R-pybox)] (R-pybox = (<i>S</i>,<i>S</i>)-<i><sup>i</sup></i>Pr-pybox, (<i>R</i>,<i>R</i>)-Ph-pybox, L = monodentate phosphonite, PPh(...

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Bibliographic Details
Main Authors: Miguel Claros, Eire de Julián, Josefina Díez, Elena Lastra, M. Pilar Gamasa
Format: Article
Language:English
Published: MDPI AG 2020-02-01
Series:Molecules
Subjects:
asymmetric catalysis
transfer hydrogenation
alcohols
ruthenium
pybox
phosphonite ligands
phosphinite ligands
Online Access:https://www.mdpi.com/1420-3049/25/4/990

Internet

https://www.mdpi.com/1420-3049/25/4/990

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