Low-Temperature Ordering in the Cluster Compound (Bi<sub>8</sub>)Tl[AlCl<sub>4</sub>]<sub>3</sub>

Low-Temperature Ordering in the Cluster Compound (Bi<sub>8</sub>)Tl[AlCl<sub>4</sub>]<sub>3</sub>

The reaction of Bi, BiCl<sub>3</sub>, and TlCl in the ionic liquid [BMIm]Cl&#183;4AlCl<sub>3</sub> (BMIm = 1-<i>n</i>-butyl-3-methylimidazolium) at 180 &#176;C yielded air-sensitive black crystals of (Bi<sub>8</sub>)Tl[AlCl<sub>4</sub&...

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Bibliographic Details
Main Authors: Maximilian Knies, Martin Kaiser, Mai Lê Anh, Anastasia Efimova, Thomas Doert, Michael Ruck
Format: Article
Language:English
Published: MDPI AG 2019-03-01
Series:Inorganics
Subjects:
bismuth
cluster compounds
hexagonal perovskite
ionic liquids
low-valent compounds
order–disorder transition
orientational disorder
polycations
pseudosymmetry
Online Access:https://www.mdpi.com/2304-6740/7/4/45

Internet

https://www.mdpi.com/2304-6740/7/4/45

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