Coordination of {Mo142} Ring to La3+ Provides Elliptical {Mo134La10} Ring with a Variety of Coordination Modes

Coordination of {Mo142} Ring to La3+ Provides Elliptical {Mo134La10} Ring with a Variety of Coordination Modes

A28-electron reduced C2h-Mo-blue 34Ǻ outer ring diameter circular ring, [Mo142O429H10(H2O)49(CH3CO2)5(C2H5CO2)]30- (≡{Mo142(CH3CO2)5(C2H5CO2)}) comprising eight carboxylate-coordinated (with disorder) {Mo2} linkers and six defect pockets in two inner rings (four and three for each, respectively), re...

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Bibliographic Details
Main Authors: Eri Ishikawa, Yutaka Yano, Toshihiro Yamase
Format: Article
Language:English
Published: MDPI AG 2009-12-01
Series:Materials
Subjects:
{Mo142}- ring
elliptical {Mo134La10}-ring
Mo-blues molecular design
La3+-coordination geometry
X-ray crystal structure
isothermal titration calorimetry (ITC)
139La-NMR
Online Access:http://www.mdpi.com/1996-1944/3/1/64/

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http://www.mdpi.com/1996-1944/3/1/64/

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