Reusable and highly enantioselective water-soluble Ru(II)-Amm-Pheox catalyst for intramolecular cyclopropanation of diazo compounds

Reusable and highly enantioselective water-soluble Ru(II)-Amm-Pheox catalyst for intramolecular cyclopropanation of diazo compounds

A reusable and highly enantioselective catalyst for the intramolecular cyclopropanation of various diazo ester and Weinreb amide derivatives was developed. The reactions catalyzed by a water-soluble Ru(II)-Amm-Pheox catalyst proceeded smoothly at room temperature, affording the corresponding bicycli...

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Bibliographic Details
Main Authors: Hamada S. A. Mandour, Yoko Nakagawa, Masaya Tone, Hayato Inoue, Nansalmaa Otog, Ikuhide Fujisawa, Soda Chanthamath, Seiji Iwasa
Format: Article
Language:English
Published: Beilstein-Institut 2019-02-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
asymmetric synthesis
carbene transfer
cyclopropanation
diazoester
intramolecular diazoamide
Ru(II)-Pheox
water-soluble catalyst
Weinreb amide
Online Access:https://doi.org/10.3762/bjoc.15.31

Internet

https://doi.org/10.3762/bjoc.15.31

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