3-Oxo-18α-olean-28,13β-olide

The title terpene, C30H46O3, is a 28,13β-lactone of oleanolic acid prepared with bismuth trifluoromethanesulfonate (OTf), Bi(OTf)3·xH2O. All rings are trans-fused. The X-ray study shows the inversion of the orientation of 18-H in the lactonization reaction. A quantum chemic...

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Bibliographic Details
Main Authors: R. C. Santos, R. M. A. Pinto, A. Matos Beja, J. A. R. Salvador, J. A. Paixão
Format: Article
Language:English
Published: International Union of Crystallography 2010-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681002903X