3-Oxo-18α-olean-28,13β-olide
The title terpene, C30H46O3, is a 28,13β-lactone of oleanolic acid prepared with bismuth trifluoromethanesulfonate (OTf), Bi(OTf)3·xH2O. All rings are trans-fused. The X-ray study shows the inversion of the orientation of 18-H in the lactonization reaction. A quantum chemic...
Main Authors: | , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2010-08-01
|
Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053681002903X |