Degenerative xanthate transfer to olefins under visible-light photocatalysis

Degenerative xanthate transfer to olefins under visible-light photocatalysis

The degenerative transfer of xanthates to olefins is enabled by the iridium-based photocatalyst [Ir{dF(CF3)ppy}2(dtbbpy)](PF6) under blue LED light irradiation. Detailed mechanistic investigations through kinetics and photophysical studies revealed that the process operates under a radical chain mec...

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Bibliographic Details
Main Authors: Atsushi Kaga, Xiangyang Wu, Joel Yi Jie Lim, Hirohito Hayashi, Yunpeng Lu, Edwin K. L. Yeow, Shunsuke Chiba
Format: Article
Language:English
Published: Beilstein-Institut 2018-12-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
energy transfer
olefin
photocatalysis
radical
xanthate
Online Access:https://doi.org/10.3762/bjoc.14.283

Internet

https://doi.org/10.3762/bjoc.14.283

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