Crystal structure of di-μ-iodido-bis[(dimethyl sulfoxide-κO)(triphenylphosphane-κP)copper(I)]

Crystal structure of di-μ-iodido-bis[(dimethyl sulfoxide-κO)(triphenylphosphane-κP)copper(I)]

The centrosymmetric dinuclear title compound, [Cu2I2(C2H6OS)2(C18H15P)2], represents the first example of a CuI complex ligated by an O-bound dimethyl sulfoxide ligand. In the crystal, the two tetrahedrally coordinated CuI atoms are bridged by two μ2-iodido ligands in an almost symmetrical rhomboid...

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Bibliographic Details
Main Authors: Rodolphe Kinghat, Michael Knorr, Yoann Rousselin, Marek M. Kubicki
Format: Article
Language:English
Published: International Union of Crystallography 2014-12-01
Series:Acta Crystallographica Section E
Subjects:
crystal structure
dinuclear CuI complexes
iodide bridges
triphenylphosphane
DMSO
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536814025203

Internet

http://scripts.iucr.org/cgi-bin/paper?S1600536814025203

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