Sequence-regulated copolymerization based on periodic covalent positioning of monomers along one-dimensional nanochannels

Achieving sequence control in polymers is limited by the relative monomer reactivity and thus often statistically random copolymers are obtained. Here the authors show sequence control in radical polymerizations by immobilising the monomer on a porous coordination polymer and subsequent polymerizati...

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Bibliographic Details
Main Authors: Shuto Mochizuki, Naoki Ogiwara, Masayoshi Takayanagi, Masataka Nagaoka, Susumu Kitagawa, Takashi Uemura
Format: Article
Language:English
Published: Nature Publishing Group 2018-01-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-017-02736-1