New library of aminosulfonyl-tagged Hoveyda–Grubbs type complexes: Synthesis, kinetic studies and activity in olefin metathesis transformations

Seven novel Hoveyda–Grubbs precatalysts bearing an aminosulfonyl function are reported. Kinetic studies indicate an activity enhancement compared to Hoveyda’s precatalyst. A selection of these catalysts was investigated with various substrates in ring-closing metathesis of dienes or enynes and cross...

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Bibliographic Details
Main Authors: Etienne Borré, Frederic Caijo, Christophe Crévisy, Marc Mauduit
Format: Article
Language:English
Published: Beilstein-Institut 2010-12-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
RCM
Online Access:https://doi.org/10.3762/bjoc.6.132