trans-(5,7,7,12,14,14-Hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene-κ4N,N′,N′′,N′′′)bis(nitrito-κN)cobalt(III) perchlorate hemihydrate

trans-(5,7,7,12,14,14-Hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene-κ4N,N′,N′′,N′′′)bis(nitrito-κN)cobalt(III) perchlorate hemihydrate

The asymmetric unit of the title CoIII complex, [Co(NO2)2(C16H32N4)]ClO4·0.5H2O, comprises two complex cations, two perchlorate anions and a water molecule of crystallization. The CoIII atoms exist within distorted octahedral N6 geometries defined by four N atoms of the macrocycle ligan...

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Bibliographic Details
Main Authors: Tapashi G. Roy, Babul C. Nath, Khadija Begum, Seik Weng Ng, Edward R. T. Tiekink
Format: Article
Language:English
Published: International Union of Crystallography 2011-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811042784

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http://scripts.iucr.org/cgi-bin/paper?S1600536811042784

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