Asymmetric Dinuclear Lanthanide(III) Complexes from the Use of a Ligand Derived from 2-Acetylpyridine and Picolinoylhydrazide: Synthetic, Structural and Magnetic Studies

Asymmetric Dinuclear Lanthanide(III) Complexes from the Use of a Ligand Derived from 2-Acetylpyridine and Picolinoylhydrazide: Synthetic, Structural and Magnetic Studies

A family of four Ln(III) complexes has been synthesized with the general formula [Ln<sub>2</sub>(NO<sub>3</sub>)<sub>4</sub>(L)<sub>2</sub>(S)] (Ln = Gd, Tb, Er, and S = H<sub>2</sub>O; <b>1</b>, <b>2</b> and <b&g...

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Bibliographic Details
Main Authors: Diamantoula Maniaki, Panagiota S. Perlepe, Evangelos Pilichos, Sotirios Christodoulou, Mathieu Rouzières, Pierre Dechambenoit, Rodolphe Clérac, Spyros P. Perlepes
Format: Article
Language:English
Published: MDPI AG 2020-07-01
Series:Molecules
Subjects:
asymmetric dinuclear lanthanide(III) complexes
dysprosium(III) and erbium(III) single-molecule magnets
magnetic properties
metal complexes of <i>N</i>’-(1-(1-pyridin-2-yl)ethylidene)pyridine-2-carbohydrazide
magnetization relaxation pathways
single-crystal X-ray structures
Online Access:https://www.mdpi.com/1420-3049/25/14/3153

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https://www.mdpi.com/1420-3049/25/14/3153

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