Crystal structure of the unusual coordination polymer catena-poly[[gold(I)-μ-1,2-bis(diphenylphosphinothioyl)ethane-κ2S:S′] dibromidoaurate(I)]
In the title compound, {[Au(C26H24P2S2)][AuBr2]}n, the gold(I) centres of the cation are coordinated by the P=S groups of the disulfide ligands to form a chain polymer parallel to the c axis. Both independent gold atoms lie on the same twofold axis, and the midpoint of the H2C—CH2 bond lies on an in...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2020-11-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989020013675 |