Electrochemical Corey–Winter reaction. Reduction of thiocarbonates in aqueous methanol media and application to the synthesis of a naturally occurring α-pyrone

Electrochemical Corey–Winter reaction. Reduction of thiocarbonates in aqueous methanol media and application to the synthesis of a naturally occurring α-pyrone

An electrochemical version of the Corey–Winter reaction was developed giving excellent results in aqueous methanol media (MeOH/H2O (80:20) with AcOH/AcONa buffer 0.5 M as supporting electrolyte), using a reticulated vitreous carbon as cathode in a divided cell. The electrochemical version is much mo...

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Bibliographic Details
Main Authors: Ernesto Emmanuel López-López, José Alvano Pérez-Bautista, Fernando Sartillo-Piscil, Bernardo A. Frontana-Uribe
Format: Article
Language:English
Published: Beilstein-Institut 2018-03-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Corey–Winter reaction
electrosynthesis
6-pentyl-2H-pyran-2-ones
reduction
thiocarbonates
Online Access:https://doi.org/10.3762/bjoc.14.41

Internet

https://doi.org/10.3762/bjoc.14.41

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