An efficient asymmetric synthesis of diacylglycerols.

A convenient preparation of 1,2-diacyl-sn-glycerol or 2,3-diacyl-sn-glycerol is described starting from allyl bromide. The latter was converted to allyl 4-methoxyphenyl ether, which is dihydroxylated using AD-mix as a catalyst to yield 3-O-(4‘-methoxyphenyl)-sn-glycerol or 1-O-(4‘-methoxyphenyl)-sn-...

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Bibliographic Details
Main Authors: C. Vilchèze, R. Bittman
Format: Article
Language:English
Published: Elsevier 1994-04-01
Series:Journal of Lipid Research
Online Access:http://www.sciencedirect.com/science/article/pii/S0022227520411861