Synthesis, characterization and crystal structure of [Cu2(LH)2]•(ClO4)2. Influence of the weak Cu•••O(perchlorate) interaction on the structure of Cu2N2O2 metallocycle

Synthesis, characterization and crystal structure of [Cu2(LH)2]•(ClO4)2. Influence of the weak Cu•••O(perchlorate) interaction on the structure of Cu2N2O2 metallocycle

The diimine-dioxime ligand, 4,9-diaza-3,10-diethyl-3,9-dodecadiene-2,11-dione bisoxime (LH2), containing a N4 donor set was prepared by Schiff base condensation of 2-hydroxyimino-3-pentanone and 1,4-diaminobutane in two ways: in protic and in aprotic solvent. Higher yield of (LH2) imine was...

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Bibliographic Details
Main Authors: Mirković Marija, Nikolić Nadežda, Mijin Dušan, Avramov-Ivić Milka, Kapor Agneš, Tomić Zoran D.
Format: Article
Language:English
Published: Serbian Chemical Society 2014-01-01
Series:Journal of the Serbian Chemical Society
Subjects:
Cu(II) complex
weak interactions
supramolecular aggregates
diimine-dioxime ligand
Online Access:http://www.doiserbia.nb.rs/img/doi/0352-5139/2014/0352-51391300120M.pdf

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http://www.doiserbia.nb.rs/img/doi/0352-5139/2014/0352-51391300120M.pdf

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