OCS photolytic isotope effects from first principles: sulfur and carbon isotopes, temperature dependence and implications for the stratosphere

The isotopic fractionation in OCS photolysis is studied theoretically from first principles. UV absorption cross sections for OCS, OC<sup>33</sup>S, OC<sup>34</sup>S, OC<sup>36</sup>S and O<sup>13&l...

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Bibliographic Details
Main Authors: J. A. Schmidt, M. S. Johnson, S. Hattori, N. Yoshida, S. Nanbu, R. Schinke
Format: Article
Language:English
Published: Copernicus Publications 2013-02-01
Series:Atmospheric Chemistry and Physics
Online Access:http://www.atmos-chem-phys.net/13/1511/2013/acp-13-1511-2013.pdf