Semiconductors as sensitisers for the radical addition of tertiary amines to electron deficient alkenes

Using heterogeneous photocatalysis, the radical addition of tertiary amines with electron deficient alkenes can be performed in high yields (up to 98%) and high facial diastereoselectivity. The photochemical induced electron transfer process initiates the radical chain reaction and inorganic semicon...

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Bibliographic Details
Main Authors: Siniša Marinković, Norbert Hoffmann
Format: Article
Language:English
Published: Hindawi Limited 2003-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/S1110662X03000308