Phosphine-Thiophenolate Half-Titanocene Chlorides: Synthesis, Structure, and Their Application in Ethylene (Co-)Polymerization
A series of novel half-titanocene complexes CpTiCl2[S-2-R-6-(PPh2)C6H3] (Cp = C5H5, 2a, R = H; 2b, R = Ph; 2c, R = SiMe3) have been synthesized by treating CpTiCl3 with the sodium of the ligands, 2-R-6-(PPh2)C6H3SNa, which were prepared by the corresponding ligands and NaH. These complexes have been...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2013-03-01
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| Series: | Catalysts |
| Subjects: | |
| Online Access: | http://www.mdpi.com/2073-4344/3/1/261 |