Time-dependent ion selectivity in capacitive charging of porous electrodes

In a combined experimental and theoretical study, we show that capacitive charging of porous electrodes in multicomponent electrolytes may lead to the phenomenon of time-dependent ion selectivity of the electrical double layers (EDLs) in the electrodes. This effect is found in experiments on capacit...

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Bibliographic Details
Main Authors: Zhao, R. (Author), van Soestbergen, M. (Author), van der Wal, A. (Author), Rijnaarts, H. H. M. (Author), Bazant, Martin Z. (Contributor), Biesheuvel, P. M. (Author)
Other Authors: Massachusetts Institute of Technology. Department of Chemical Engineering (Contributor), Massachusetts Institute of Technology. Department of Mathematics (Contributor)
Format: Article
Language:English
Published: Elsevier, 2016-02-11T02:48:30Z.
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