Synthesis and Characterization of Mononuclear, Pseudotetrahedral Cobalt(III) Compounds

The preparation and characterization of two mononuclear cobalt(III) tropocoronand complexes, [Co(TC-5,5)](BF[subscript 4]) and [Co(TC-6,6)](BPh[subscript 4]), are reported. The cobalt(III) centers exist in rare pseudotetrahedral conformations, with twist angles of 65° and 74° for the [Co(TC-5,5]+ an...

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Bibliographic Details
Main Authors: Kozhukh, Julia (Contributor), Minier, Mikael Antoine (Contributor), Lippard, Stephen J. (Contributor)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor)
Format: Article
Language:English
Published: American Chemical Society (ACS), 2016-08-11T15:08:17Z.
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