Direct Observation of Intermediates Involved in the Interruption of the Bischler-Napieralski Reaction

The first mechanistic investigation of electrophilic amide activation of α,α-disubstituted tertiary lactams and the direct observation of key intermediates by in situ FTIR, 1H, 13C, and 19F NMR in our interrupted Bischler-Napieralski-based synthetic strategy to the aspidosperma alkaloids, including...

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Bibliographic Details
Main Authors: White, Kolby L. (Contributor), Mewald, Marius (Contributor), Movassaghi, Mohammad (Contributor)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor)
Format: Article
Language:English
Published: American Chemical Society (ACS), 2017-06-26T19:56:57Z.
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