Regiodivergent and Diastereoselective CuH-Catalyzed Allylation of Imines with Terminal Allenes

A copper-catalyzed, chemoselective hydrometalation process enables the use of simple allenes as allylmetal nucleophile surrogates in imine allylation reactions. By modulating the nitrogen-protecting group, either highly branched- or linear-selective addition can be achieved from the same allene. Bot...

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Bibliographic Details
Main Authors: Liu, Richard Y. (Author), Yang, Yang (Contributor), Buchwald, Stephen L. (Author), Liu, Richard (Contributor), Buchwald, Stephen Leffler (Contributor)
Format: Article
Language:English
Published: Wiley-Blackwell, 2018-01-10T15:53:04Z.
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