On the Incompatibility of lithium-O₂ Battery Technology with CO₂

On the Incompatibility of lithium-O₂ Battery Technology with CO₂

When solubilized in a hexacarboxamide cryptand anion receptor, the peroxide dianion reacts rapidly with CO₂ in polar aprotic organic media to produce hydroperoxycarbonate (HOOCO₂- ) and peroxydicarbonate (-O₂ COOCO₂-). Peroxydicarbonate is subject to thermal fragmentation into two equivalents of the...

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Bibliographic Details
Main Authors: Chow, Gary K. (Author), Lopez, Nazario (Author), Britt, David R. (Author), Nocera, Daniel G. (Author), Zhang, Shiyu (Contributor), Nava, Matthew Jordan (Contributor), Wu, Gang (Contributor), Cummins, Christopher C (Contributor)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor)
Format: Article
Language:English
Published: Royal Society of Chemistry (RSC), 2018-01-23T16:36:51Z.
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