Convergent and Biomimetic Enantioselective Total Synthesis of (−)-Communesin F

Convergent and Biomimetic Enantioselective Total Synthesis of (−)-Communesin F

The first biomimetic enantioselective total synthesis of (-)-communesin F based on a late-stage heterodimerization and aminal exchange is described. Our synthesis features the expedient diazene-directed assembly of two advanced fragments to secure the congested C3a-C3a' linkage in three steps,...

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Bibliographic Details
Main Authors: Lathrop, Stephen (Contributor), Pompeo, Matthew M (Contributor), Chang, Wen-Tau (Contributor), Movassaghi, Mohammad (Contributor)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor)
Format: Article
Language:English
Published: American Chemical Society (ACS), 2018-04-20T21:22:15Z.
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