Second-Coordination-Sphere Assisted Selective Colorimetric Turn-on Fluoride Sensing by a Mono-Metallic Co(II) Hexacarboxamide Cryptand Complex

The preparation of a selective turn-on colorimetric fluoride sensor was achieved through single cobalt(II) ion insertion into a macrobicyclic cryptand. Monometallic [Co(mBDCA-5t-H₃)]− (1) and [Zn(mBDCA-5t-H₃)]− (2) complexes were prepared in 74 and 84% yields, respectively. Structural characterizati...

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Bibliographic Details
Main Authors: Stauber, Julia M. (Contributor), Alliger, Glen Edward (Contributor), Nocera, Daniel G (Contributor), Cummins, Christopher C (Contributor)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor), Cummins, Christopher C. (Contributor)
Format: Article
Language:English
Published: American Chemistry Society, 2018-06-26T15:21:24Z.
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